This study represents the method of application of W.S(Work Sampling) to determine job sequence. The result shows job sequence which has the came performance measure of optimal job sequence is selected by average number of 199 sampling. In the case, the optimal job sequence is not selected within the sampling number of 921 which satisfy the reliability of 99.5% and precision of 99%, the deviation is very little which 0.73%. This improves the possibility of application of W.S method to select optimal job sequence is very high.